- Yuchen Shang, Zhaodong Liu, Jiajun Dong, Mingguang Yao, Zhenxing Yang, Quanjun Li, Chunguang Zhai, Fangren Shen, Xuyuan Hou, Lin Wang, Nianqiang Zhang, Wei Zhang, Rong Fu, Jianfeng Ji, Xingmin Zhang, He Lin, Yingwei Fei, Bertil Sundqvist, Weihua Wang, Bingbing Liu. Ultrahard bulk amorphous carbon from collapsed fullerene. Nature, 2021; 599 (7886): 599 DOI: 10.1038/s41586-021-03882-9
Function follows form when it comes to understanding the properties of a material. How its atoms are chemically bonded to each other, and their resulting structural arrangement, determines a material’s physical qualities — both those that are observable by the naked eye and those that are only revealed by scientific probing.
Carbon is unrivaled in its ability to form stable structures — alone and in combination with other elements. Some forms of carbon are highly organized, with repeating crystalline lattices. Others are more disordered, a quality termed amorphous.
The type of bond holding a carbon-based material together determine its hardness. For example, soft graphite has two-dimensional bonds and hard diamond has three-dimensional bonds.
“The synthesis of an amorphous carbon material with three-dimensional bonds has been a long-standing goal,” explained Fei. “The trick is to find the right starting material to transform with the application of pressure.”
“For decades Carnegie researchers have been at the forefront of the field, using laboratory techniques to generate extreme pressures to produce novel materials or mimic the conditions found deep inside planets,” added Carnegie Earth and Planets Laboratory Director Richard Carlson.
Because of its extremely high melting point, it’s impossible to use diamond as the starting point to synthesize diamond-like glass. However, the research team, led by Jilin University’s Bingbing Liu and Mingguang Yao — a former Carnegie visiting scholar — made their breakthrough by using a form of carbon composed of 60 molecules arranged to form a hollow ball. Informally called a buckyball, this Nobel Prize-winning material was heated just enough to collapse its soccer-ball-like structure to induce disorder before turning the carbon to crystalline diamond under pressure.
The team used a large-volume multi-anvil press to synthesize the diamond-like glass. The glass is sufficient large for characterization. Its properties were confirmed using a variety of advanced, high-resolution techniques for probing atomic structure.
“The creation of a glass with such superior properties will open the door to new applications,” Fei explained. “The use of new glass materials hinges on making large pieces, which has posed a challenge in the past. The comparatively lower temperature at which we were able to synthesize this new ultrahard diamond glass makes mass production more practical.”
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New ultrahard diamond glass synthesized